Preheat the oven to 350°F. Spray three 8-inch round cake pans with nonstick spray, line the bottoms with parchment, and set aside.
In a large bowl, sift the flour, granulated sugar, unsweetened cocoa powder, and baking soda together. Set aside.
2½ cups all-purpose flour, 2 cups granulated sugar, ¾ cup unsweetened cocoa powder, 2 teaspoons baking soda
In a medium bowl, whisk the buttermilk, melted butter, eggs, and vanilla extract together.
1 cup buttermilk, 1 cup salted butter, 2 large eggs, 2 teaspoons pure vanilla extract
Pour the wet ingredients into the dry ingredients, then gently fold together just until combined.
Divide the cake batter evenly between the prepared cake pans (about 462 grams per pan). Bake for 30-33 minutes, or until a toothpick inserted in middle comes out clean.
Remove the cakes from oven and let cakes cool in pans for 15 minutes. Remove from the pans and set on a wire rack to finish cooling, about 1-2 hours.
Once the cakes have completely cooled, wrap each one in plastic wrap and chill in the refrigerator for 2 hours.