Preheat oven to 350°F. Spray three 8-inch round cake pans with nonstick spray and line the inside bottom of each pan with parchment paper (the parchment paper will help the cakes slide easily out of the pan once baked and cooled). Set pans aside for now.
In a medium bowl, stir the flour, cocoa powder, baking powder, and baking soda together. Set aside.
3¼ cups all-purpose flour, 1 cup unsweetened cocoa powder, 2 teaspoons baking powder, 1 teaspoon baking soda
In the bowl of a stand mixer fitted with the paddle attachment, beat the butter, brown sugar, and granulated sugar on high until mixed well, about 2 minutes.
1½ cups unsalted butter, 1½ cups brown sugar, ¾ cup granulated sugar
Beat the eggs and vanilla extract into the butter mixture until well combined.
4 large eggs, 1 tablespoon pure vanilla extract
Beat half of the flour mixture into the wet ingredients. Beat this on low speed just until combined. Do not overmix.
Beat in all of the buttermilk just until combined. Again, don’t overmix.
½ cup buttermilk
On low speed, beat in the remaining flour mixture just until combined.
Stir in the melted chocolate by hand until well mixed. Do not use the electric beaters for this step.
12 ounces semisweet Baker’s chocolate
Divide the cake batter evenly between the 3 prepared cake pans (about 672 grams per pan). Try to get the same amount in each pan so that they bake at the same speed.
Bake in oven for 30 minutes or until toothpick inserted in middle of each comes out clean or with moist crumbs.
Remove cakes from oven and let cakes cool in pans for 15 minutes. After 15 minutes, remove cakes from pans and let cool completely on a wire rack.
Once cakes have completely cooled to room temperature, wrap each cake individually in food-safe plastic wrap and place cakes in fridge for at least 1 hour. Chilling the cakes in the fridge before frosting will help them hold their shape and not crumble during decorating.
Removed chilled cakes from the fridge and use a large serrated knife to cut any dome tops off cakes so they have flat tops. These cakes bake up pretty flat (like brownies) so there won’t be a lot to cut off the tops.